Measuring MeHQ (Polymerization Inhibitor)

Polymerization inhibitors are chemicals which stabilize reactive monomers and prevent spontaneous polymerization. If too little inhibitor is added to a reactive monomer, polymerization can occur in pipes or vessels and require mechanical removal. On the other hand, if too much inhibitor is added, the final product may have difficulty polymerizing at the intended stage. Monitoring hydroquinone monomethyl ether (MeHQ) in Acrylonitrile.

MeHQ is usually added as an inhibitor to acrylonitrile (a precursor to polyacrylonitrile fibers for the textile industry). The concentration of MeHQ in the monomer needs to be regulated to avoid spontaneous polymerization (to polyacrylonitrile) as well as waste of MeHQ. MeHQ has a distinct UV absorbance curve which allows the OMA system to easily monitor its real-time concentration. The full spectrum analysis is critical for differentiating MeHQ absorbance from other absorbing impurities in the sample. The OMA continuously outputs the MeHQ reading to the plant’s main computer, providing new measurements at 1-5 second intervals for extremely tight process control.

Read more: https://aai.solutions/application-notes/measuring-polymerization-inhibitor#MeHQ

A dynamic study of CO oxidation on supported platinum

Catalytic oxidation of CO on alumina-supported platinum was studied in a tubular isothermal reactor with applied concentration transients. A completely automated reactor system capable of switching frequencies as high as 0.2 Hz was constructed. Concentration cycling resulted in reaction rates that were much higher than the maximum rate achievable at steady-state operation. Mapping of the time-averaged carbon dioxide production rate in the timeperiod duty-fraction plane, resulted in a unique… CONTINUE READING